Electron Spin Resonance Line Shapes and Saturation in the Slow Motional Regionla

@inproceedings{Freed2001ElectronSR,
  title={Electron Spin Resonance Line Shapes and Saturation in the Slow Motional Regionla},
  author={Jack H. Freed and G. Bruno and Carl F. Polnaszek},
  year={2001}
}
The stochastic Liouville method is developed and applied in a manner appropriate to ana1yl;e the problem of esr line shapes and saturation in the slow-motional region with particular emphasis on rotational diffusion. Detailed unsaturated line shape solutions are obtained for axial and asymmetric g tensors and axial dipolar tensors. These line shapes are compared to the predicted rigid-solid spectral shapes. In particular, it is shown that the pseudo-secular dipolar terms make significant… CONTINUE READING

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