Electron Paramagnetic Resonance Characteristics and Crystal Structure of a Tutton Salt Analog: Copper Doped Cadmium Creatininium Sulfate.

@article{Colaneri2020ElectronPR,
  title={Electron Paramagnetic Resonance Characteristics and Crystal Structure of a Tutton Salt Analog: Copper Doped Cadmium Creatininium Sulfate.},
  author={Michael J. Colaneri and Simon J. Teat and Jacqueline Vitali},
  journal={The journal of physical chemistry. A},
  year={2020}
}
Electron Paramagnetic Resonance and crystallographic studies on copper-doped cadmium creatininium sulfate (CdCrnS) were undertaken to study the characteristics of a copper-hexahydrate complex in an organic analog of Tutton's salt. X-ray diffraction experiments determined the crystal structure of CdCrnS at both 100 K and 298 K. CdCrnS, like Tutton salt, crystallizes in the monoclinic space group P21/n. The unit cell contains two cadmium hexahydrate complexes, four creatininium ions, four… 
3 Citations
Effect of the Lattice Field on the Electronic Structure and Dynamics of Copper-Hexahydrate in Tutton Salts.
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The correlation found here reinforces a recent view that the coupling of the copper complex to the surrounding crystal lattice is the major determinant of these dynamics, and the lattice potentials lack any significant temperature dependency and thus do not appear to be responsible for changes in the EPR patterns.
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Using first-principles calculations, we show that the origin of the intrinsic a1g(∼3z2 – r2)–b1g(∼x2 – y2) splitting, Δint, in tetragonal transition-metal complexes and the variations of the cubic
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