Electrochemical study of a dendritic family at the water/1,2-dichloroethane interface.


The transfer of six dendritric molecules, DMs, across the water/1,2-dichloroethane interface was investigated using cyclic voltammetry. From the variation of peak potential with pH, two different mechanisms of transfer were postulated depending on the nature of the molecules. Voltammetric parameters were employed to evaluate the hydrophilic/hydrophobic character and calculate the acid dissociation constant of these molecules. The results were explained taking into account the nature and multiplicity of functional surface groups.

DOI: 10.1021/la704052b

Cite this paper

@article{Caldern2008ElectrochemicalSO, title={Electrochemical study of a dendritic family at the water/1,2-dichloroethane interface.}, author={Marcelo Calder{\'o}n and Lorena M . A . Monzon and M Giovanna Martinelli and Ana V Juarez and Miriam Cristina Strumia and Lidia M Yudi}, journal={Langmuir : the ACS journal of surfaces and colloids}, year={2008}, volume={24 12}, pages={6343-50} }