Electrochemical intramolecular aminooxygenation of unactivated alkenes.

Abstract

An electrochemical approach to the intramolecular aminooxygenation of unactivated alkenes has been developed. This process is based on the addition of nitrogen-centered radicals, generated through electrochemical oxidation, to alkenes followed by trapping of the cyclized radical intermediate with 2,2,6,6-tetramethylpiperidine-N-oxyl radical (TEMPO… (More)
DOI: 10.1002/chem.201404078

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