Electrochemical Kinetics of Cyanometalate Complexes in Aqueous Solution at High Pressures.

@article{Fu1999ElectrochemicalKO,
  title={Electrochemical Kinetics of Cyanometalate Complexes in Aqueous Solution at High Pressures.},
  author={Yansong Fu and Thomas W. Swaddle},
  journal={Inorganic chemistry},
  year={1999},
  volume={38 5},
  pages={876-880}
}
For the aqueous couples Os(CN)(6)(3-/4-), Mo(CN)(8)(3-/4-), and W(CN)(8)(3-/4-), volumes of reaction DeltaV(Ag/AgCl) relative to Ag/AgCl/4.0 mol L(-)(1) KCl and volumes of activation DeltaV(el)() for the electrode reactions are reported. Values of DeltaV(Ag/AgCl) are consistent with a very small increase in the metal-carbon bond length on reduction in each case, the main component of DeltaV(Ag/AgCl) (other than that of the reference electrode) being electrostrictive solvation change. For media… CONTINUE READING