Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts

Abstract

The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH3)4Cl2]+ of quasi-octahedral symmetry D4h are produced. The composition and structure of nascent complex ions have been studied. During electrochemical reduction of [Rh(NH3)4Cl2]+ complexes, the synthesis of Rh nanoparticles, as well as Fe, Cu, and Mo nanocoatings, were realized.

DOI: 10.1186/s11671-017-2108-7

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Cite this paper

@inproceedings{Kochetova2017ElectrochemicalBA, title={Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts}, author={Svetlana Kochetova and Anastasiya Savchuk and Dmytro Shakhnin and V. P. Malyshev}, booktitle={Nanoscale research letters}, year={2017} }