Einige neue Iridium-Komplexe von Phosphor-yliden /Some New Iridium Complexes of Phosphorus Ylides

@article{Fraser1979EinigeNI,
  title={Einige neue Iridium-Komplexe von Phosphor-yliden /Some New Iridium Complexes of Phosphorus Ylides},
  author={Torquil E. M. Fraser and H. H. Fuller and Hubert Schmidbaur},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  year={1979},
  volume={34},
  pages={1218 - 1220}
}
  • Torquil E. M. Fraser, H. H. Fuller, Hubert Schmidbaur
  • Published 1979
  • Chemistry
  • Zeitschrift für Naturforschung B
  • Abstract From the iridium complexes [(1,5-C8H12)IrCl]2, [(C8H14)2IrCl]2 and [(C6H5)3P]2lr(CO)Cl, and the ylides (CH3)3P = CH2 and (CH3)3P = N-P(CH3)2 = CH2, a number of organoiridium compounds has been synthesized. Whereas with (CH3)3P = CH2 the transylidation reaction is very slow and simple addition with formation of sparingly soluble products prevails, the double ylide forms cyclic complexes quite readily. These ylide chelates were characterized by analytical and spectroscopic data. 

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