Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

Ming Zhang, Ablimit Abdukader, Yong Fu, Chengjian Zhu
Published 2012 in Molecules

Abstract

An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good to excellent yields at room temperature.

DOI: 10.3390/molecules17032812

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Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

Abstract

Topics

4 Figures and Tables

Cited By

References

The interaction of gold(I) cations with 1,3-dienes.

Ca(CF3COO)2: An efficient Lewis acid catalyst for chemo- and regio-selective enamination of β-dicarbonyl compounds

A novel method for the synthesis of β-enaminones using Cu-nanoparticles as catalyst

Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex

Solid-State Synthesis of β-Enamino Ketones from Solid 1,3-Dicarbonyl Compounds and Ammonium Salts or Amines

A revision for the synthesis of β-enaminones in solvent free conditions: efficacy of different supported heteropoly acids as active and reusable catalysts

Development of a Bulk Enabling Route to Maraviroc (UK-427,857), a CCR-5 Receptor Antagonist

Simple and Efficient Synthesis of 3-Aminopropenones and 3-Aminopropenoates Catalyzed by Copper (II) Nitrate Trihydrate under Solvent-Free Conditions

Synthesis of Pyrazoles, Diazepines, Enaminones, and Enamino Esters Using 12-Tungstophosphoric Acid as a Reusable Catalyst in Water

p-Toluenesulfonylmethyl Isocyanide (TosMIC) and Indium Manifold Strategy to Access β-Keto-(E)-enamino Esters from 1,3-Dicarbonyl Compounds

Slides referencing similar topics

Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

Abstract

Topics

4 Figures and Tables

Cited By

References

The interaction of gold(I) cations with 1,3-dienes.

Ca(CF3COO)2: An efficient Lewis acid catalyst for chemo- and regio-selective enamination of β-dicarbonyl compounds

A novel method for the synthesis of β-enaminones using Cu-nanoparticles as catalyst

Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex

Solid-State Synthesis of β-Enamino Ketones from Solid 1,3-Dicarbonyl Compounds and Ammonium Salts or Amines

A revision for the synthesis of β-enaminones in solvent free conditions: efficacy of different supported heteropoly acids as active and reusable catalysts

Development of a Bulk Enabling Route to Maraviroc (UK-427,857), a CCR-5 Receptor Antagonist

Simple and Efficient Synthesis of 3-Aminopropenones and 3-Aminopropenoates Catalyzed by Copper (II) Nitrate Trihydrate under Solvent-Free Conditions

Synthesis of Pyrazoles, Diazepines, Enaminones, and Enamino Esters Using 12-Tungstophosphoric Acid as a Reusable Catalyst in Water

p-Toluenesulfonylmethyl Isocyanide (TosMIC) and Indium Manifold Strategy to Access β-Keto-(E)-enamino Esters from 1,3-Dicarbonyl Compounds

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