Efficient oxidation of alcohols to carbonyl compounds with molecular oxygen catalyzed by N-hydroxyphthalimide combined with a Co species

@article{Iwahama2000EfficientOO,
  title={Efficient oxidation of alcohols to carbonyl compounds with molecular oxygen catalyzed by N-hydroxyphthalimide combined with a Co species},
  author={Iwahama and Yoshino and Keitoku and Sakaguchi and Ishii},
  journal={The Journal of organic chemistry},
  year={2000},
  volume={65 20},
  pages={6502-7}
}
Highly efficient catalytic oxidation of alcohols with molecular oxygen by N-hydroxyphthalimide (NHPI) combined with a Co species was developed. The oxidation of 2-octanol in the presence of catalytic amounts of NHPI and Co(OAc)2 under atmospheric dioxygen in AcOEt at 70 degrees C gave 2-octanone in 93% yield. The oxidation was significantly enhanced by adding a small amount of benzoic acid to proceed smoothly even at room temperature. Primary alcohols were oxidized by NHPI in the absence of any… CONTINUE READING

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Primary alcohols were oxidized by NHPI in the absence of any metal catalyst to form the corresponding carboxylic acids in good yields .
Primary alcohols were oxidized by NHPI in the absence of any metal catalyst to form the corresponding carboxylic acids in good yields .
Efficient oxidation of alcohols to carbonyl compounds with molecular oxygen catalyzed by N - hydroxyphthalimide combined with a Co species .
Efficient oxidation of alcohols to carbonyl compounds with molecular oxygen catalyzed by N - hydroxyphthalimide combined with a Co species .
Highly efficient catalytic oxidation of alcohols with molecular oxygen by N - hydroxyphthalimide ( NHPI ) combined with a Co species was developed .
Highly efficient catalytic oxidation of alcohols with molecular oxygen by N - hydroxyphthalimide ( NHPI ) combined with a Co species was developed .
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