• DOI:10.1126/science.1228604
• Corpus ID: 37971858

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites

@article{Lee2012EfficientHS,
  title={Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites},
  author={Michael M. Lee and Jo{\"e}l Teuscher and Tsutomu Miyasaka and Takurou N. Murakami and Henry J. Snaith},
  journal={Science},
  year={2012},
  volume={338},
  pages={643 - 647}
}

• Michael M. Lee, J. Teuscher, +2 authors H. Snaith
• Published 2 November 2012
• Chemistry, Materials Science
• Science

Perovskite Photovoltaics For many types of low-cost solar cells, including those using dye-sensitized titania, performance is limited by low open-circuit voltages. Lee et al. (p. 643, published online 4 October; see the Perspective by Norris and Aydil) have developed a solid-state cell in which structured films of titania or alumina nanoparticles are solution coated with a lead-halide perovskite layer that acts as the absorber and n-type photoactive layer. These particles are coated with a spirobifluorene organic-hole conductor in a solar cell with transparent oxide and metal contacts. For the alumina particles, power conversion efficiencies of up to 10.9% were obtained. Mesostructured alumina acts as an insulating scaffold for the assembly of very thin films of n- and p-type semiconductors. The energy costs associated with separating tightly bound excitons (photoinduced electron-hole pairs) and extracting free charges from highly disordered low-mobility networks represent fundamental losses for many low-cost photovoltaic technologies. We report a low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight. This “meso-superstructured solar cell” exhibits exceptionally few fundamental energy losses; it can generate open-circuit photovoltages of more than 1.1 volts, despite the relatively narrow absorber band gap of 1.55 electron volts. The functionality arises from the use of mesoporous alumina as an inert scaffold that structures the absorber and forces electrons to reside in and be transported through the perovskite.