Effects of unstirred layers or transport number discontinuities on the transient and steady-state current-voltage relationships of membranes.


The effects of current-induced electrolyte accumulation and depletion on the electrical properties of a two-layered membrane system have been examined. The membrane consisted of a charged, ion permselective layer and an uncharged, non-selective layer. The model was designed to reveal the properties of membranes possessing long pores with ionic charges at… (More)


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