Effects of nonequilibrium on velocity and plate height in reactive capillary electrophoresis.

@article{Newman2005EffectsON,
  title={Effects of nonequilibrium on velocity and plate height in reactive capillary electrophoresis.},
  author={Carl I D Newman and Victoria L. McGuffin},
  journal={Electrophoresis},
  year={2005},
  volume={26 21},
  pages={4016-25}
}
Models for velocity and plate height for reactive CE are developed under the formalism of generalized nonequilibrium theory, as described by Giddings. The resultant equations are consistent with chromatographic theory and validated with an independent stochastic simulation. Moreover, unlike prior methods for CE, this model allows calculation of thermodynamic equilibrium constants and kinetic rate constants from a single, undistorted peak. The theoretical development shows that velocity is… CONTINUE READING