Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene
@article{Hantanasirisakul2019EffectsOS, title={Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene}, author={Kanit Hantanasirisakul and Mohamed Alhabeb and Alexey Lipatov and Kathleen Maleski and Babak Anasori and Pol Salles and Chanoknan Ieosakulrat and Pasit Pakawatpanurut and Alexander Sinitskii and Steven J. May and Yury Gogotsi}, journal={Chemistry of Materials}, year={2019} }
MXenes, a relatively new class of two-dimensional (2D) transition-metal carbides, carbonitrides, and nitrides, exhibit unique properties such as high electronic conductivity, a wide range of optical characteristics, hydrophilicity, and mechanical stability. Because of the high electronic conductivity, MXenes have shown promise in many applications, such as energy storage, electromagnetic interference shielding, antennas, and transparent coatings. 2D titanium carbide (Ti3C2Tx, where Tx…
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References
SHOWING 1-10 OF 65 REFERENCES
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)
- ChemistryAdvanced materials
- 2018
2D transition metal carbides, carbonitrides, and nitrides, known as MXenes, are a rapidly growing family of 2D materials with close to 30 members experimentally synthesized, and dozens more studied…
Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)
- Materials Science
- 2017
Two-dimensional (2D) transition metal carbides, carbonitrides, and nitrides (MXenes) were discovered in 2011. Since the original discovery, more than 20 different compositions have been synthesized…
Two-dimensional transition metal carbides and nitrides (MXenes) for biomedical applications.
- Chemistry, Materials ScienceChemical Society reviews
- 2018
This review introduces the preparation methods and surface modifications with respect to MXenes, and highlights their various biomedical applications, such as with biosensors, antibacterial materials, bioimaging probes, therapeutics, and theranostics.
Fabrication of Ti3C2Tx MXene Transparent Thin Films with Tunable Optoelectronic Properties
- Materials Science
- 2016
MXenes, a new class of 2D transition metal carbides and carbonitrides, show great promise in supercapacitors, Li‐ion batteries, fuel cells, and sensor applications. A unique combination of their…
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
- Materials ScienceChemistry of materials : a publication of the American Chemical Society
- 2014
This work reports on the fabrication of ∼1 × 1 cm2 Ti3C2 films by selective etching of Al, from sputter-deposited epitaxial Ti3AlC 2 films, in aqueous HF or NH4HF2, and opens the door for the use of MXenes in electronic, photonic, and sensing applications.
Control of MXenes’ electronic properties through termination and intercalation
- Materials ScienceNature Communications
- 2019
Two-dimensional transition metal carbides and nitrides (MXenes) have emerged as highly conductive and stable materials, of promise for electronic applications, and in situ electric biasing and transmission electron microscopy are used to investigate the effect of surface termination and intercalation on electronic properties.
Highly Conductive Optical Quality Solution‐Processed Films of 2D Titanium Carbide
- Materials Science
- 2016
MXenes comprise a new class of solution‐dispersable, 2D nanomaterials formed from transition metal carbides and nitrides such as Ti3C2. Here, it is shown that 2D Ti3C2 can be assembled from aqueous…
Atomic Defects in Monolayer Titanium Carbide (Ti3C2Tx) MXene.
- Materials ScienceACS nano
- 2016
The atomic structure of freestanding monolayer Ti3C2Tx flakes prepared via the minimally intensive layer delamination method is determined and it is determined that the Ti vacancy concentration can be controlled by the etchant concentration during preparation.
2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes).
- Materials Science, ChemistryNanoscale
- 2017
This study shows how gas treatment synthesis such as ammoniation can transform carbide MXenes into 2D nitrides with higher electrical conductivities and metallic behavior, opening a new avenue in 2D materials synthesis.
Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes.
- Materials ScienceACS applied materials & interfaces
- 2018
Two-dimensional (2D) particles, including transition metal carbides (MXenes), often exhibit large lateral-size polydispersity in delaminated colloidal solutions. This heterogeneity results in…