Effective catalysis of simple metalloporphyrins for cyclohexane oxidation with air in the absence of additives and solvents

@inproceedings{Guo2003EffectiveCO,
  title={Effective catalysis of simple metalloporphyrins for cyclohexane oxidation with air in the absence of additives and solvents},
  author={Can-cheng Guo and Ming-Fu Chu and Qiang Liu and Yang Liu and Dong-cai Guo and Xiao-qin Liu},
  year={2003}
}
Abstract Simple iron, manganese and cobalt tetraphenylporphyrins were synthesized and used to catalyze cyclohexane oxidation with air in the absence of additives and solvents. These simple metalloporphyrins were first found to be the very effective catalysts for cyclohexane oxidation with air when the reaction temperature was higher than 100 °C and pressure was greater than 0.4 MPa. The research results showed that the metalloporphyrins type, temperature, pressure and catalyst concentration… CONTINUE READING

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Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

  • Frontiers of Chemical Science and Engineering
  • 2012
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