Effective Rotation–Pseudorotation Hamiltonian forX3-Type Molecules: Application to theB̃–X̃Transition of Na3

@article{Ohashi1997EffectiveRH,
  title={Effective Rotation–Pseudorotation Hamiltonian forX3-Type Molecules: Application to theB̃–X̃Transition of Na3},
  author={N. Ohashi and Makiko Tsuura and J. T. Hougen and W. Ernst and S. Rakowsky},
  journal={Journal of Molecular Spectroscopy},
  year={1997},
  volume={184},
  pages={22-34}
}
  • N. Ohashi, Makiko Tsuura, +2 authors S. Rakowsky
  • Published 1997
  • Physics
  • Journal of Molecular Spectroscopy
  • Abstract A formalism has been developed for rotation–pseudorotation energy levels of X 3 -type molecules in orbitally nondegenerate electronic states (so that Jahn–Teller complications are absent). The formalism includes electron spin, but excludes nuclear spin effects. Correlation diagrams are presented connecting rotational energy levels in the high-barrier asymmetric-rotor limit to those in the low-barrier free-rotor quasi-symmetric-top limit. By applying the formalism to theBstate of Na 3… CONTINUE READING
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