Effect of the metallicity on the capacitance of gold-aqueous sodium chloride interfaces.

@article{Serva2021EffectOT,
  title={Effect of the metallicity on the capacitance of gold-aqueous sodium chloride interfaces.},
  author={Alessandra Serva and Laura Scalfi and Benjamin Rotenberg and Mathieu Salanne},
  journal={The Journal of chemical physics},
  year={2021},
  volume={155 4},
  pages={
          044703
        }
}
Electrochemistry experiments have established that the capacitance of electrode-electrolyte interfaces is much larger for good metals, such as gold and platinum, than for carbon-based materials. Despite the development of elaborate electrode interaction potentials, to date molecular dynamics simulations are not able to capture this effect. Here, we show that changing the width of the Gaussian charge distribution used to represent the atomic charges in gold is an effective way to tune its… Expand

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