EPR Discovery of a New Pressure-Induced Low-Spin Phase in (2Me–5Et–PyH)[Fe(Th–5Cl–Sa)2]

Abstract

(Received April 6, 2006) Electron paramagnetic resonance studies of the high-spin (HS) ↔ low-spin (LS) transition in 2-methyl–5-ethyl–pyridine–5-chloro–salicylalthiosemicarbazonatoferrate(III) performed under hydrostatic pressure up to 500 MPa in a temperature range of 80–310 K have revealed two modifications of the low spin complexes: low-pressure (LS1… (More)

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