EFFECTS OF THE ELECTRONIC SPIN TRANSITIONS OF IRON IN LOWER MANTLE MINERALS: IMPLICATIONS FOR DEEP MANTLE GEOPHYSICS AND GEOCHEMISTRY

@article{Lin2013EFFECTSOT,
  title={EFFECTS OF THE ELECTRONIC SPIN TRANSITIONS OF IRON IN LOWER MANTLE MINERALS: IMPLICATIONS FOR DEEP MANTLE GEOPHYSICS AND GEOCHEMISTRY},
  author={Jung-Fu Lin and S. Speziale and Z. Mao and H. Marquardt},
  journal={Reviews of Geophysics},
  year={2013},
  volume={51},
  pages={244-275}
}
[1] We have critically reviewed and discussed currently available information regarding the spin and valence states of iron in lower mantle minerals and the associated effects of the spin transitions on physical, chemical, and transport properties of the deep Earth. A high-spin to low-spin crossover of Fe2+ in ferropericlase has been observed to occur at pressure-temperature conditions corresponding to the middle part of the lower mantle. In contrast, recent studies consistently show that Fe2… Expand
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  • 20
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  • 6
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  • 12
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References

SHOWING 1-10 OF 250 REFERENCES
Spin transition of iron in the Earth's lower mantle
  • 90
  • Highly Influential
Electronic spin states of ferric and ferrous iron in the lower-mantle silicate perovskite
  • 67
  • PDF
Spin transition of iron in magnesiowüstite in the Earth's lower mantle
  • 271
  • PDF
The spin state of iron in minerals of Earth's lower mantle
  • 125
  • PDF
Electronic spin state of iron in lower mantle perovskite.
  • J. Li, V. Struzhkin, +7 authors G. Shen
  • Chemistry, Medicine
  • Proceedings of the National Academy of Sciences of the United States of America
  • 2004
  • 179
  • Highly Influential
  • PDF
Effects of spin transition on diffusion of Fe2+in ferropericlase in Earth's lower mantle
  • 15
  • PDF
Effects of the Fe3 + spin transition on the properties of aluminous perovskite—New insights for lower-mantle seismic heterogeneities
  • 87
  • Highly Influential
  • PDF
Effect of composition, structure, and spin state on the thermal conductivity of the Earth's lower mantle
  • 34
  • Highly Influential
Iron Partitioning in Earth's Mantle: Toward a Deep Lower Mantle Discontinuity
  • 447
  • Highly Influential
Mössbauer modeling to interpret the spin state of iron in (Mg,Fe)SiO3 perovskite
  • 79
  • Highly Influential
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