Dual stereoselection in the addition of diethylzinc to benzaldehyde by using highly structurally close ligands.

Abstract

The screening of the catalytic activity in the diethylzinc reaction of a series of easily accessible (1S)-ketopinic-acid derived hydroxyamides, designed by key structure modifications of a parent highly active related bis(hydroxyamide), has allowed to find the first case of dual stereoselection in highly structurally close ligands of such interesting… (More)
DOI: 10.1002/chir.21994

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