Dual signaling system with an extended-tetrathiafulvalene-phenanthroline dyad acting as an electrooptical cation chemosensor.

@article{HardouinLerouge2012DualSS,
  title={Dual signaling system with an extended-tetrathiafulvalene-phenanthroline dyad acting as an electrooptical cation chemosensor.},
  author={Marie Hardouin-Lerouge and Bertrand Chesneau and Magali Allain and Pi{\'e}trick Hudhomme},
  journal={The Journal of organic chemistry},
  year={2012},
  volume={77 5},
  pages={
          2441-5
        }
}
An efficient synthesis of unprecedented fused extended-tetrathiafulvalene-dipyridoquinoxaline (exTTF-dpq) dyad is described through the Horner-Wardsworth-Emmons olefination methodology from the dipyrido[3,2-a:2',3'-c]-benzo[3,4]phenazine-11,16-quinone (NqPhen) ligand starting material. This exTTF-dpq dyad is demonstrated to act as a dual redox and colorimetric sensor for cations exploiting the proximity between the redox tetrathiafulvalene and the optical phenanthroline detecting sites. Its… CONTINUE READING
BETA

From This Paper

Figures, tables, and topics from this paper.

Similar Papers

Loading similar papers…