Driving force dependence of rates for nonadiabatic proton and proton-coupled electron transfer: conditions for inverted region behavior.

Abstract

The driving force dependence of the rate constants for nonadiabatic electron transfer (ET), proton transfer (PT), and proton-coupled electron transfer (PCET) reactions is examined. Inverted region behavior, where the rate constant decreases as the reaction becomes more exoergic (i.e., as DeltaG(0) becomes more negative), has been observed experimentally for… (More)
DOI: 10.1021/jp907808t

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