Donor-acceptor interactions in tri(phosphonio)methanide dications [(Ph3P)2CP(X)Ph2]2+ (X = H, Me, CN, NCS, OH, Cl, OTf, F).

@article{Yogendra2017DonoracceptorII,
  title={Donor-acceptor interactions in tri(phosphonio)methanide dications [(Ph3P)2CP(X)Ph2]2+ (X = H, Me, CN, NCS, OH, Cl, OTf, F).},
  author={Sivathmeehan Yogendra and Felix Hennersdorf and Antonio Bauz{\'a} and Antonio Frontera and Reinald Fischer and Jan J Weigand},
  journal={Dalton transactions},
  year={2017},
  volume={46 44},
  pages={15503-15511}
}
The impact of the strongly electron donating carbodiphosphorane moiety in the series of tri(phosphonio)methanide dications as triflate salts [(Ph3P)2CP(X)Ph2][OTf]2 (X = H, Me, CN, NCS, OH, Cl, OTf, F) deriving from [(Ph3P)2CPPh2][OTf] (19[OTf]) is presented. The influence of the introduced substituents X on the electronic structures of these dications is… CONTINUE READING