Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?

@article{Qian2015DoesTT,
  title={Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?},
  author={Kang Qian and Jos{\'e} J. Baldov{\'i} and Shangda Jiang and Alejandro Gaita-Ari{\~n}o and Yiquan Zhang and Jacob Overgaard and Bingwu Wang and Eugenio Coronado and Song Gao},
  journal={Chemical science},
  year={2015},
  volume={6 8},
  pages={4587-4593}
}
A dysprosium based single-ion magnet is synthesized and characterized by the angular dependence of the single-crystal magnetic susceptibility. Ab initio and effective electrostatic analyses are performed using the molecular structures determined from single crystal X-ray diffraction at 20 K, 100 K and 300 K. Contrary to the common assumption, the results… CONTINUE READING