Diversity of copper(I) complexes showing thermally activated delayed fluorescence: basic photophysical analysis.

@article{Czerwieniec2015DiversityOC,
  title={Diversity of copper(I) complexes showing thermally activated delayed fluorescence: basic photophysical analysis.},
  author={Rafał Czerwieniec and Hartmut Yersin},
  journal={Inorganic chemistry},
  year={2015},
  volume={54 9},
  pages={
          4322-7
        }
}
A comparison of three copper(I) compounds [1, Cu(dppb)(pz2Bph2); 2, Cu(pop)(pz2Bph2); 3, Cu(dmp)(phanephos)(+)] that show pronounced thermally activated delayed fluorescence (TADF) at ambient temperature demonstrates a wide diversity of emission behavior. In this study, we focus on compound 1. A computational density functional theory (DFT)/time-dependent DFT approach allows us to predict detailed photophysical properties, while experimental emission studies over a wide temperature range down… CONTINUE READING
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