Divergent synthesis of three classes of aryl N-glycosides by solvent control.

Abstract

Aryl glycosides represent a group of molecules with immense biological applications and implications. While the syntheses of aryl C-glycosides and O-glycosides have been studied extensively, the preparation for aryl N-glycosides is relatively unexplored. By employing 1,4-naphthoquinone and glycosyl azides undergoing a [3 + 2] cycloaddition, we have… (More)
DOI: 10.1021/jo8020133

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