Dithiocarbamate complexes of Ti(IV) alkoxides: synthesis, characterization, and electrochemistry.

@article{Donzelli2009DithiocarbamateCO,
  title={Dithiocarbamate complexes of Ti(IV) alkoxides: synthesis, characterization, and electrochemistry.},
  author={Alberto Donzelli and Pierre G. Potvin},
  journal={Inorganic chemistry},
  year={2009},
  volume={48 9},
  pages={
          4171-8
        }
}
Isopropoxy- and tert-butoxy-tris(dithiocarbamato)titanium(IV) complexes of five dithiocarbamate ligands were prepared and characterized by LDI-MS, (1)H NMR, (13)C NMR, and elemental analysis, as well as by crystallographic determination of two examples. Both showed strongly pi-coordinated alkoxy groups and two separate dithiocarbamate coordination environments that, in solution, were in rapid exchange. Cyclic voltammetry in CH(2)Cl(2) revealed irreversible but reproducible oxidation peaks… CONTINUE READING
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