Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology.

@article{lvarez2015DistortionPO,
  title={Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology.},
  author={Santiago Noriega {\'A}lvarez},
  journal={Chemical reviews},
  year={2015},
  volume={115 24},
  pages={13447-83}
}
A continuous shape measures analysis of the coordination polyhedra of a host of transition metal complexes with bi- and multidentate ligands discloses the distortion pathway associated with each particular topology of the chelate rings formed. The basic parameter that controls the degree of distortion is the metal-donor atom bond distance that induces nonideal bond angles due to the rigidity of the ligands. Thus, the degree of distortion within each family of complexes depends on the atomic… CONTINUE READING
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