Dissociation dynamics of the methylsulfonyl radical and its photolytic precursor CH3SO2Cl.

Abstract

The dissociation dynamics of methylsulfonyl radicals generated from the photodissociation of CH(3)SO(2)Cl at 193 nm is investigated by measuring product velocities in a crossed laser-molecular beam scattering apparatus. The data evidence three primary photodissociation channels of the precursor: S-Cl fission to produce Cl atoms and ground electronic state… (More)
DOI: 10.1063/1.3159555

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