Disproportionation channel of self-reaction of hydroxyl radical, OH + OH → H2O + O, studied by time-resolved oxygen atom trapping.

@article{Manuvesh2012DisproportionationCO,
  title={Disproportionation channel of self-reaction of hydroxyl radical, OH + OH → H2O + O, studied by time-resolved oxygen atom trapping.},
  author={Sangwan Manuvesh and Lev N. Krasnoperov},
  journal={The journal of physical chemistry. A},
  year={2012},
  volume={116 48},
  pages={
          11817-22
        }
}
The disproportionation channel of the self-reaction of hydroxyl radicals, OH + OH → H(2)O + O (1a) was studied using pulsed laser photolysis coupled to transient UV-vis absorption spectroscopy over the 298-414 K temperature and 3-10 bar pressure ranges (bath gas He). To distinguish channel 1a from the recombination channel 1b, OH + OH → H(2)O(2) (1b), time-resolved trapping of oxygen atoms, produced in channel 1a, was used. The ozone produced in the reaction of oxygen atoms with molecular… CONTINUE READING
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