Disperse Amphiphilic Submicron Particles as Non-Covalent Supports for Cationic Homogeneous Catalysts

Abstract

A simple method for the effective immobilization of homogeneous catalysts on polystyrene colloids via non-covalent binding is demonstrated. Stable latices with sufficiently high loading of accessible borate anions are prepared via emulsion polymerization. Incorporation of cationic rhodium complexes, supported via their borate counter-anion is efficient, and… (More)

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