Directing the Crystallization of Dehydro[24]annulenes into Supramolecular Nanotubular Scaffolds.

Abstract

The self-assembly of a series of dehydro[24]annulene derivatives into columnar stacks has been examined for its latent ability to form π-conjugated carbon-rich nanotubular structures through topochemical polymerizations. We have studied the parameters affecting self-assembly, including the nature of the substituent and crystallization conditions, using 10… (More)
DOI: 10.1021/jacs.6b01939

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