Directed synthesis of μ-1,3,5 bridged dicyanamides by thermal decomposition of μ-1,5 bridged precursor compounds.


Reaction of transition-metal dicyanamides with pyridazine leads to the formation of the ligand-rich 1 : 2 (1 : 2 = ratio between metal salt and organic co-ligand) compounds [M(dca)(2)(pydz)(2)](n) (dca = dicyanamide, pydz = pyridazine) with M = Mn (1-Mn), Fe (1-Fe), Co (1-Co), Ni (1-Ni). In their crystal structures linear polymeric M-(dca)(2)-M chains are… (More)
DOI: 10.1039/c0dt00864h


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