Direct visualization of the chemical mechanism in SERRS of 4-aminothiophenol/metal complexes and metal/4-aminothiophenol/metal junctions.


Direct visualization of photoinduced tunneling charge transfer (TCT) in an Au(5)/para-aminothiophenol (PATP)/Ag(6) junction in which Au and Ag clusters form the first and second layer, respectively, is provided by the charge difference density (see picture; green and red stand for holes and electrons, respectively). We theoretically investigate the… (More)
DOI: 10.1002/cphc.200800596


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