This paper investigates the direct upconversion sensitization luminescence of the ErYb co-doped oxyfluoride glass (ErYb: FOG), fluoride glass (ErYb: ZBLAN) and pentaphosphate noncrystalline (ErYb: PP) excited by a 966 nm diode laser. The splendid upconversion luminescence phenomenon is found. It is resulted from that the Yb3+ concentration in rather high, the energy transfer among Er(3+)-Yb3+ and Yb(3+)-Yb3+ ions is rather strong. An important fact is found that the direct upconversion sensitization luminescence of ErYb: FOG is about 100-100,000 times greater than that of ErYb: PP. And meanwhile it is interesting that the upconversion luminescence intensity of ErYb: FOG is near to that of ErYb: ZBLAN. It is significant to enhance the comprehensive level of up-conversion luminescence.