Direct potential fit analysis of the X 1Σg+ state of Rb2: Nothing else will do!

@article{Seto2000DirectPF,
  title={Direct potential fit analysis of the X 1$\Sigma$g+ state of Rb2: Nothing else will do!},
  author={Jenning Y. Seto and R. L. Roy and J. Verg{\`e}s and C. Amiot},
  journal={Journal of Chemical Physics},
  year={2000},
  volume={113},
  pages={3067-3076}
}
High resolution A-X emission data involving vibrational levels of the ground X 1Σg+ electronic state up to v″=113, spanning 99.8% of the potential well, have been acquired for three isotopomers of Rb2. While a good fit (σf=1.03) to the 12 148 transition frequencies (with uncertainties ±0.001 cm−1) is obtained from an unconstrained combined-isotopomer Dunham-type analysis, it requires a large number (62) of expansion parameters, and the resulting empirical centrifugal distortion constants (CDCs… Expand

Figures and Tables from this paper

...
1
2
3
4
5
...

References

SHOWING 1-10 OF 46 REFERENCES
...
1
2
3
4
5
...