Direct potential fit analysis of the X 1Σ+ ground state of CO

@article{Coxon2004DirectPF,
  title={Direct potential fit analysis of the X 1$\Sigma$+ ground state of CO},
  author={J. A. Coxon and P. Hajigeorgiou},
  journal={Journal of Chemical Physics},
  year={2004},
  volume={121},
  pages={2992-3008}
}
A collection of 21,559 highly precise spectroscopic line positions from pure rotational and vibration-rotational spectra for seven isotopomers of carbon monoxide in the X1sigma+ ground electronic state has been employed in direct least-squares fits of the rovibrational Hamiltonian operator obtained from Watson's work [J. Mol. Spectrosc. 80, 411 (1980)] and that obtained by Herman and Ogilvie [Adv. Chem. Phys 103, 187 (1998)]. Fully analytical models are used for the various functions, including… Expand
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