Direct oxidative allylic and vinylic amination of alkenes through selenium catalysis.

@article{Trenner2013DirectOA,
  title={Direct oxidative allylic and vinylic amination of alkenes through selenium catalysis.},
  author={Johanna Trenner and Christian Depken and Thomas Weber and Alexander Breder},
  journal={Angewandte Chemie},
  year={2013},
  volume={52 34},
  pages={8952-6}
}
Direct Oxidative Allylic and Vinylic Amination of Alkenes through Selenium Catalysis Bringing “N” into the game: The direct chemoselective nitrogenation of unactivated alkenes can be achieved through oxidative selenium catalysis (see scheme). This protocol provides a broad variety of allylic imides in yields of up to 89 % using N-fluorobenzenesulfonimide (NFSI) as the terminal oxidant and nitrogen source. Furthermore, an unprecedented selenium-catalyzed vinylic C(sp)–H nitrogenation was… CONTINUE READING
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