Direct observation of the gas-phase Criegee intermediate (CH2OO).

@article{Taatjes2008DirectOO,
  title={Direct observation of the gas-phase Criegee intermediate (CH2OO).},
  author={Craig A Taatjes and Giovanni Meloni and Talitha M Selby and Adam J Trevitt and David L Osborn and Carl J Percival and Dudley E. Shallcross},
  journal={Journal of the American Chemical Society},
  year={2008},
  volume={130 36},
  pages={11883-5}
}
Carbonyl oxide species play a key role in tropospheric oxidation of organic molecules and in low-temperature combustion processes. In the late 1940s, Criegee first postulated the participation of carbonyl oxides, now often called "Criegee intermediates," in ozonolysis of alkenes. However, despite decades of effort, no gas phase Criegee intermediate has before been observed. As a result, knowledge of gas phase carbonyl oxide reactions has heretofore been inferred by indirect means, with derived… CONTINUE READING

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