Direct observation and quantification of CO₂ binding within an amine-functionalized nanoporous solid.

Abstract

Understanding the molecular details of CO(2)-sorbent interactions is critical for the design of better carbon-capture systems. Here we report crystallographic resolution of CO(2) molecules and their binding domains in a metal-organic framework functionalized with amine groups. Accompanying computational studies that modeled the gas sorption isotherms, high… (More)
DOI: 10.1126/science.1194237

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