Direct construction of vicinal all-carbon quaternary stereocenters in natural product synthesis.

Abstract

Molecules containing vicinal all-carbon quaternary stereocenters are found in many secondary metabolites, and they exhibit a variety of biological and pharmacological activities. However, the construction of such a structural motif remains a significant challenge in natural product synthesis. Only in recent years have considerable efforts been made to… (More)
DOI: 10.1039/c5np00046g

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