Direct Cyclization of Tertiary Aryl Amines with Iodonium Ylides.


Described herein is a direct cyclization of simple tertiary aryl amines with iodonium ylides leading to a broad range of N-heterocycles. Completely different from the known reactivity of iodonium ylides, the finding reported herein is that an iodonium ylide is capable of cleaving a C(sp3 )-H bond and accepting two hydrogen atoms of a tertiary aryl amine… (More)
DOI: 10.1002/anie.201800389


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