Dioxygen reactivity of iron(ii)-gentisate/1,4-dihydroxy-2-naphthoate complexes of N4 ligands: oxidative coupling of 1,4-dihydroxy-2-naphthoate.

@article{Rahaman2019DioxygenRO,
  title={Dioxygen reactivity of iron(ii)-gentisate/1,4-dihydroxy-2-naphthoate complexes of N4 ligands: oxidative coupling of 1,4-dihydroxy-2-naphthoate.},
  author={Rubina Rahaman and Sandip Munshi and Sridhar Banerjee and Biswarup Chakraborty and Sarmistha Bhunia and Tapan Kanti Paine},
  journal={Dalton transactions},
  year={2019}
}
  • Rubina Rahaman, Sandip Munshi, +3 authors Tapan Kanti Paine
  • Published in Dalton transactions 2019
  • Chemistry, Medicine
  • The influence of supporting ligands and co-ligands on the dioxygen reactivity of a series of iron(ii) complexes, [(6-Me3-TPA)FeII(GN-H)]+ (1), [(6-Me3-TPA)FeII(DHN-H)]+ (1a), [(BPMEN)FeII(GN-H)]+ (2), [(BPMEN)FeII(DHN-H)]+ (2a), [(TBimA)FeII(GN-H)]+ (3), and [(TBimA)FeII(DHN-H)]+ (3a) (GN-H2 = 2,5-dihydroxybenzoic acid and DHN-H2 = 1,4-dihydroxy-2-naphthoic acid) of N4 ligands, is presented. The iron(ii)-gentisate complexes react with dioxygen to afford the corresponding iron(iii) species. On… CONTINUE READING

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