Dinuclear triple-stranded complexes of Re(V) with bis(benzene-o-dithiolato) ligands.

@article{Gancheff2012DinuclearTC,
  title={Dinuclear triple-stranded complexes of Re(V) with bis(benzene-o-dithiolato) ligands.},
  author={Jorge S Gancheff and F Ekkehardt Hahn},
  journal={Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy},
  year={2012},
  volume={98},
  pages={62-9}
}
The reaction of K(2)ReCl(6) with 1,2-bis(2,3-dimercaptobenzamido)ethane (H(4)-1), and 1,2-bis(2,3-dimercaptobenzamido)benzene (H(4)-2) in the presence of Na(2)CO(3) in methanol affords dinuclear complexes of Re(V). Experimental evidence supports the presence of self-assembled complexes with two {Re(S(2)C(6)H(3))(3)} units connected in a triple-stranded… CONTINUE READING