# Diamagnetic d-Orbitals Drive Magnetic Structure Selection in the Double Perovskite Ba2MnTeO6

@article{Mustonen2020DiamagneticDD,
title={Diamagnetic d-Orbitals Drive Magnetic Structure Selection in the Double Perovskite Ba2MnTeO6},
author={Otto Mustonen and Charlotte E. Pughe and Helen C. Walker and Heather M. Mutch and Gavin B. G. Stenning and Fiona C. Coomer and Edmund J. Cussen},
journal={Chemistry of Materials},
year={2020},
volume={32},
pages={7070-7079}
}
• O. Mustonen, +4 authors E. Cussen
• Published 1 June 2020
• Physics, Materials Science
• Chemistry of Materials
B-site ordered A2B′B″O6 double perovskites have a variety of applications as magnetic materials. Here, we show that diamagnetic d10 and d0 B″ cations have a significant effect on the magnetic inter...
6 Citations

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## References

SHOWING 1-10 OF 71 REFERENCES
Exchange interactions in antiferromagnetic complex perovskites
Magnetic interactions between Ni2+ spins in ordered complex perovskites, cubic Ba2NiWO6 and tetragonal Sr2NiWO6, have been investigated. Analysis of the spin-wave excitation spectrum has shown that
Magnetic structure of Sr2CuWO6.
• Materials Science, Medicine
Journal of physics. Condensed matter : an Institute of Physics journal
• 2014
Magnetic structure of the double perovskite Sr2CuWO6 was determined from neutron powder diffraction data, showing that the three-dimensional magnetic long-range order is caused by relatively strong antiferromagnetic next-nearest-neighbor interactions.
A2B′B″O6 perovskites: A review
• Chemistry
• 2015
Abstract The B-site substituted perovskite oxides A2B′B″O6 have in the recent decades gained an increasing amount of interest due to their various interesting properties and possible applications.
Magnetic order and electronic structure of 5d3 double perovskite Sr2ScOsO6
The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the
Magnetic ordering in ordered complex Cu perovskite probed by μSR and neutron diffraction
• Chemistry
• 2007
Abstract Magnetic properties of antiferromagnetic (AF) B-site-ordered perovskite Ba 2 CuWO 6 have been investigated by μ SR and neutron diffraction. Interesting features of this compound are the
Geometrically frustrated magnetic materials
The current state of efforts to understand the phenomenon of geometric magnetic frustration is described in the context of several key materials. All are transition metal oxides which crystallize
Crystal Structure and Magnetic Properties of B-Site Ordered Perovskite-type Oxides A2CuB′O6 (A=Ba, Sr; B′=W, Te)
• Chemistry
• 1999
Abstract Four cuprate perovskites with the general formula A2CuB′O6 (A=Ba, Sr; B′=W, Te) were synthesized and the structural and the magnetic properties were investigated. Among four samples,
Structure and magnetic properties of Sr2NiAO6 (A = W, Te)
• Chemistry
• 2000
Abstract Crystal structures and magnetic properties of the B-site ordered perovskites Sr 2 NiWO 6 and Sr 2 NiTeO 6 were investigated. Powder X-ray diffraction analysis revealed that Sr 2 NiWO 6 and
Long- and short-range magnetism in the frustrated double perovskite Ba2MnWO6
The structural and magnetic properties of the face-centered cubic double perovskite Ba2MnWO6 were investigated using neutron powder diffraction, DC-magnetometry, muon spin relaxation and inelastic
Active role of nonmagnetic cations in magnetic interactions for double-perovskite Sr2BOsO6(B = Y, In, Sc)
• Materials Science, Physics
• 2016
Using first-principles density functional theory, we have investigated the electronic and magnetic properties of recently synthesized and characterized 5d double-perovskites Sr2BOsO6 (B=Y, In, Sc).