Determination of rate and equilibrium constants for the reactions between electron transfer mediators and proteins by linear sweep voltammetry.

@article{Parker1997DeterminationOR,
  title={Determination of rate and equilibrium constants for the reactions between electron transfer mediators and proteins by linear sweep voltammetry.},
  author={Vernon D. Parker and Alan Roddick and Lance C Seefeldt and Hong Zhi Wang and Guojun Zheng},
  journal={Analytical biochemistry},
  year={1997},
  volume={249 2},
  pages={212-8}
}
Redox proteins undergo measurable charge transfer at electrodes only under special circumstances, while they readily take part in electron transfer reactions with mediators in solution. Advantage was taken of the latter fact to develop a new method to study the kinetics and equilibria of protein-mediator electron transfer reactions. It was shown that rate… CONTINUE READING