Determination of protonation constants of some fluorinated polyamines by means of 13C NMR data processed by the new computer program HypNMR2000. Protonation sequence in polyamines

@article{Frassineti2003DeterminationOP,
  title={Determination of protonation constants of some fluorinated polyamines by means of 13C NMR data processed by the new computer program HypNMR2000. Protonation sequence in polyamines},
  author={C. Frassineti and L. Alderighi and P. Gans and A. Sabatini and A. Vacca and S. Ghelli},
  journal={Analytical and Bioanalytical Chemistry},
  year={2003},
  volume={376},
  pages={1041-1052}
}
  • C. Frassineti, L. Alderighi, +3 authors S. Ghelli
  • Published 2003
  • Chemistry, Medicine
  • Analytical and Bioanalytical Chemistry
    • Abstract.The pKa values of 6-fluoro-4,8-diazadodecane-1,12-diamine (6-fluorospermine) (1), 6,6-difluoro-4,8-diazadodecane-1,12-diamine (6,6-difluorospermine) (2), 6-fluoro-4-azaoctane-1,8-diamine (6-fluorospermidine) (3) and 6,6-difluoro-4-azaoctane-1,8-diamine (6,6-difluorospermidine) (4) in D2O solution have been determined at 40 °C from 13C NMR chemical shifts data using the new computer program HypNMR2000. The enthalpies of protonation of compounds 1–4 and the parent amines spermine (5) and… CONTINUE READING
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