Determination of acid dissociation constants by capillary electrophoresis.

@article{Poole2004DeterminationOA,
  title={Determination of acid dissociation constants by capillary electrophoresis.},
  author={Salwa K. Poole and Sneha Ramesh Patel and Karen A Dehring and Heather L Workman and Colin F. Poole},
  journal={Journal of chromatography. A},
  year={2004},
  volume={1037 1-2},
  pages={445-54}
}
Capillary electrophoresis affords a simple, automated approach for the measurement of pKa values in the range 2-11 at a throughput of less than 1 h per sample per instrument. Agreement with literature values is usually within 0.20 log units with a precision better than 0.07 log units. The attractive features of capillary electrophoresis for pKa measurements are: (1) conventional instrumentation with a high level of automation are suitable for all measurements; (2) because it is a separation… CONTINUE READING

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