Designed synthesis of 3D covalent organic frameworks.

@article{ElKaderi2007DesignedSO,
  title={Designed synthesis of 3D covalent organic frameworks.},
  author={Hani M El-Kaderi and Joseph R. Hunt and Jose L. Mendoza-Cortes and Adrien P. C{\^o}t{\'e} and Robert Edward Taylor and M. O'Keeffe and Omar M Yaghi},
  journal={Science},
  year={2007},
  volume={316 5822},
  pages={268-72}
}
Three-dimensional covalent organic frameworks (3D COFs) were synthesized by targeting two nets based on triangular and tetrahedral nodes: ctn and bor. The respective 3D COFs were synthesized as crystalline solids by condensation reactions of tetrahedral tetra(4-dihydroxyborylphenyl) methane or tetra(4-dihydroxyborylphenyl)silane and by co-condensation of triangular 2,3,6,7,10,11-hexahydroxytriphenylene. Because these materials are entirely constructed from strong covalent bonds (C-C, C-O, C-B… CONTINUE READING

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