Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes

@article{Camasso2015DesignSA,
  title={Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes},
  author={Nicole M Camasso and M. Sanford},
  journal={Science},
  year={2015},
  volume={347},
  pages={1218 - 1220}
}
Taking advantage of four for a nickel Metal atoms change their oxidation state—i.e., lose or gain electrons—relatively easily. This is a major reason why metal compounds accelerate so many chemical reactions. Camasso and Sanford now report a straightforward way to prepare complexes of nickel in the +4 oxidation state, based on careful tuning of the coordination environment around the metal center (see the Perspective by Riordan). These complexes could prove useful in coupling carbon to oxygen… Expand
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References

SHOWING 1-10 OF 40 REFERENCES
Organometallic nickel(III) complexes relevant to cross-coupling and carbon-heteroatom bond formation reactions.
Palladium-catalyzed ligand-directed C-H functionalization reactions.
Emergence of palladium(IV) chemistry in synthesis and catalysis.
Cross-coupling reaction of alkyl halides with grignard reagents catalyzed by Ni, Pd, or Cu complexes with pi-carbon ligand(s).
A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species.
Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations.
A stable tetraalkyl complex of nickel(IV).
Nickel-catalyzed direct arylation of C(sp3)-H bonds in aliphatic amides via bidentate-chelation assistance.
High-oxidation-state palladium catalysis: new reactivity for organic synthesis.
  • K. Muñiz
  • Chemistry, Medicine
  • Angewandte Chemie
  • 2009
High-valent organometallic copper and palladium in catalysis
...
1
2
3
4
...