Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes

@article{Camasso2015DesignSA,
  title={Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes},
  author={Nicole M Camasso and M. Sanford},
  journal={Science},
  year={2015},
  volume={347},
  pages={1218 - 1220}
}
Taking advantage of four for a nickel Metal atoms change their oxidation state—i.e., lose or gain electrons—relatively easily. This is a major reason why metal compounds accelerate so many chemical reactions. Camasso and Sanford now report a straightforward way to prepare complexes of nickel in the +4 oxidation state, based on careful tuning of the coordination environment around the metal center (see the Perspective by Riordan). These complexes could prove useful in coupling carbon to oxygen… Expand
119 Citations
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