Derivation of free energy expressions for tube models from coarse-grained slip-link models.

Abstract

We present the free energy of a single-chain mean-field model for polymer melt dynamics, which uses a continuous (tube-like) approximation to the discrete entanglements with surrounding chains, but, in contrast to previous tube models, includes fluctuations in the number density of Kuhn steps along the primitive path and in the degree of entanglement. The… (More)
DOI: 10.1063/1.4730170

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